Characteristics of Covalent Bond Homework Help, Tutoring
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Bond Length, Bond Energies, Bond Angles Assignment Help, Tutor Help
Characteristics of Covalent Bond
As discussed in our earlier sessions, covalent bond is a bond formed between atoms of
comparable electronegativity. The electrons involved in the bond formation are shared
by both the atoms. Now, let us see some of the characteristics of covalent bond.
- Bond Length:
- Bond Energies:
- Bond Angles:
Formation of bond between two atoms does not bring the two atoms very close
to each other. There will be certain distance between the two atoms involved
in the bond formation. That average distance between the nuclei of the two
atoms is termed as bond length or bond distance. It is measured in terms of
angstrom units, where 1 Aο = 10-8 cm. Formation of multiple bonds between
atoms reduces the bond length. Another reason for decrease in bond length
in involvement of s-orbitals that are smaller in size compared to p-orbitals.
Factors such as electronegativity, hybridization and steric effects do have
influence on the bond length.
It is the amount of energy liberated or consumed when a covalent bond is broken
or formed. Every bond has its own unique bond energy values. Generally, bond
dissociation energy is used to state the strength of the bond. Greater the bond
dissociation energy, greater will the strength of the bond and more stable will
be the compound. In compounds with multiple bonds, bond dissociation energy is
the sum of the bond dissociation energies of the same type of bonds present in
the molecule.
Bond energy increases with the formation of multiple bonds. Hence, compounds with
triple bonds are more stable than those with single bond. In case of sigma bond
and the pie bond, sigma bond is stronger. Another factor affecting the bond energy
is the presence of lone pair of electrons. Bond energy decreases with the increase
in the number of lone pair of electrons. Hence, among C-C, N-N, O-O, O-O has lower
bond energy due to the presence of more number of lone pair of electrons compared
to the other two. The reason for lowered bond energy in compounds with a lone pair
of electrons is due to the presence of electrostatic repulsion between the lone
pair of electrons.
The average angle between the bonded orbitals is termed as bond angle and is represented
as θ. Due to the movement of the molecules, the bond angle keeps changing. Hence, the
bond angle of a molecule is taken as an average of these angles. Bond angle is greatly
determined by the orbitals involved in the bond formation. For example, the compounds
with bonds formed by p-orbitals have a bond angle of 90ο. However, all bonds formed
involving p-orbitals do not have the above mentioned 90ο. This is due to the action
of various forces such as repulsion between atoms or groups attached to the central
atom, hybridization of bonding orbitals and the repulsion due to presence of lone
pair or non-bonding electrons.
For example in case of H-S-H the bond angle is 92ο 26 instead of the regular
90ο.This is due to the presence of repulsion between hydrogen atoms attached to the
central sulphur atoms.
Similarly, the bond angle of water molecule is 105ο instead of the regular
90ο due to the presence of lone pair of electrons on the oxygen atom.
Solved problems
- Reason for deviation of the regular tetrahedral bond angle in water molecule is due to
- Presence of lone pair of electrons
- Repulsion between hydrogen atoms attached to the oxygen
- Hybridization
- All the above
- Which of the following is right in case of bond energies
- C-C> N-N> O-O
- C-C< N-N< O-O
- N-N< O-O< C-C
- O-O>C-C> N-N
- Bond angle of H2S molecule is
- 92ο 26
- 90 ο
- 105 ο
- None
- Unit for measuring bond length is
- Angstrom units
- Centimeter
- Meter
- None
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